4-dodecylbenzenesulfonic acid (dbsa): an efficient, eco-friendly and chemoselective catalyst for the synthesis of 1, 1- diacetates under solvent-free conditions at room temperature

Authors

a. z. sardarian

abstract

4-dodecylbenzenesulfonic acid (dbsa) has been shown to be an efficient, mild, green, stable and chemoselective brønsted acid catalyst for the synthesis of 1, 1-diacetates (acylals) of aldehydes under solvent-free conditions. the mild condition, eco-friendly, excellent yields, short reaction times and using an easily available, inexpensive and reusable catalyst are important features of this method.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

Natural Kaolin supported sulfuric acid as an efficient catalyst for the preparation of 1, 1-diacetates under solvent-free conditions

A facile and efficient method for the preparation of 1,1-diacetates of aldehydes is improved. The acidified kaolin with sulfuric acid (2 % w/w) catalyzed 1,1-diacetates formation from aldehydes in solvent-free conditions. Both aromatic and aliphatic aldehydes gave high yields (85-95 %) of the corresponding 1, 1-diacetates. Advantages of this method are the use of inexpensive and selective catal...

full text

Natural Kaolin supported sulfuric acid as an efficient catalyst for the preparation of 1, 1-diacetates under solvent-free conditions

A facile and efficient method for the preparation of 1,1-diacetates of aldehydes is improved. The acidified kaolin with sulfuric acid (2 % w/w) catalyzed 1,1-diacetates formation from aldehydes in solvent-free conditions. Both aromatic and aliphatic aldehydes gave high yields (85-95 %) of the corresponding 1, 1-diacetates. Advantages of this method are the use of inexpensive and selective catal...

full text

Dipyridine cobalt chloride as an efficient and chemoselective catalyst for the synthesis of 1,1-diacetates under solvent-free conditions

1,1-Diacetates(acylals) were prepared by direct condensation of various aldehydes with acetic anhydride using dipyridine cobalt chloride (CoPy2Cl2) as an efficient and green catalyst under solvent-free conditions at room temperature. The important features of this catalyst method are that the catalyst is solid, stable at high temperatures, soluble in water, stable in air, immiscible in common o...

full text

Tannic acid: A Green Catalyst for the Eco-friendly Synthesis of 2,3-dihydroquinazolin-4(1H)-ones under Solvent Free Conditions

A new, facile, cost effective, and eco-friendly protocol is reported for the synthesis of 2,3-dihydroquinazoline-4-(1H)-ones exploring tannic acid as a novel, inexpensive, andbiodegradable catalyst. A variety of dihydroquinazolins were prepared from aromatic aldehydesand anthranilamide using catalytic amount of tannic acid under solvent free conditions.Operational simplicity, high yield, and hi...

full text

TiCl2/nano-γ-Al2O3 as an efficient catalyst for synthesis of substituted pyrroles under solvent-free conditions at room temperature

TiCl2/nano-γ-Al2O3 as a new heterogeneous Lewis acid catalyst was synthesized and characterized by FE-SEM, XRD, FT-IR, EDS, XRF, BET and TGA. N-substituted pyrroles have been synthesized via Paal–Knorr reaction in the presence of TiCl2/nano-γ-Al2O3 at room temperature under solvent-free conditions.

full text

TiCl2/nano-γ-Al2O3 as an efficient catalyst for synthesis of substituted pyrroles under solvent-free conditions at room temperature

TiCl2/nano-γ-Al2O3 as a new heterogeneous Lewis acid catalyst was synthesized and characterized by FE-SEM, XRD, FT-IR, EDS, XRF, BET and TGA. N-substituted pyrroles have been synthesized via Paal–Knorr reaction in the presence of TiCl2/nano-γ-Al2O3 at room temperature under solvent-free conditions.

full text

My Resources

Save resource for easier access later


Journal title:
iranian journal of science and technology (sciences)

ISSN 1028-6276

volume 37

issue 3 2013

Keywords
[ 4 , ' d o d e c y l b e n z e n e s u l f o n i c a c i d ' , ' s o l v e n t ' , ' f r e e ' , ' c h e m o s e l e c t i v e ' , 1 , 1 , ' d i a c e t a t e s ' , ' a l d e h y d e s ' , ' a c e t i c a n h y d r i d e ' ]

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023